Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation.

نویسندگان

  • Kohei Matsuzaki
  • Tomoya Hiromora
  • Hideki Amii
  • Norio Shibata
چکیده

We disclose herein the perfluoroalkylation of alkenes catalyzed by trifluoroethoxy-coated zinc phthalocyanine under irradiation of visible light. Perfluoroalkyl iodides were nicely incorporated into unsaturated substrates, including alkyne, to provide perfluoroalkyl and iodide adducts in moderate to good yields. Trifluoromethylation is also possible by trifluoromethyl iodide under the same reaction conditions. The mechanistic study is discussed.

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عنوان ژورنال:
  • Molecules

دوره 22 7  شماره 

صفحات  -

تاریخ انتشار 2017